New magnetic nanocomposite Fe3O4@Saponin/Cu(II) as an effective recyclable catalyst for the synthesis of aminoalkylnaphthols via Betti reaction

Majid Heidarpour; Marziyeh Kiani; Hossein Anaraki-Ardakani; Parizad Rezaei; Saeed Parvizi Ghaleh; Reza Ahmadi; Mohammad Maleki

doi:10.1016/j.steroids.2022.109170

New magnetic nanocomposite Fe₃O₄@Saponin/Cu(II) as an effective recyclable catalyst for the synthesis of aminoalkylnaphthols via Betti reaction

Steroids. 2023 Mar:191:109170. doi: 10.1016/j.steroids.2022.109170. Epub 2022 Dec 29.

Authors

Majid Heidarpour¹, Marziyeh Kiani², Hossein Anaraki-Ardakani³, Parizad Rezaei⁴, Saeed Parvizi Ghaleh⁵, Reza Ahmadi⁶, Mohammad Maleki²

Affiliations

¹ Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran. Electronic address: majid.heidarpour67@gmail.com.
² Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran.
³ Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran. Electronic address: hosseinanaraki@yahoo.com.
⁴ Department of Chemical Engineering, Abadan Branch, Islamic Azad University, Abadan, Iran.
⁵ Faculty of Petroleum and Natural Gas Engineering, Sahand University of Technology, Tabriz, Iran.
⁶ Department of Environmental Engineering, West Tehran Branch, Islamic Azad University, Tehran, Iran.

PMID: 36587779
DOI: 10.1016/j.steroids.2022.109170

Abstract

In this research, a new magnetic nanocomposite Fe₃O₄@Saponin/Cu(II) based on quillaja saponin was prepared and the catalyst structure was characterized thoroughly using FT-IR, EDS, TGA, XRD, VSM, HR-TEM, SEM, ICP, BET analyzes. The catalyst prepared in the three-component synthesis of several Betti bases, 1-(α-aminoalkyl)naphthols, under environmentally friendly conditions was used. The advantage of this reaction is the high efficiency of the products and the short reaction time. Furthermore, Fe₃O₄@Saponin/Cu(II) nano-catalyst is recoverable magnetically and is reusable for other processes with no reduction in its activity.

Keywords: Green chemistry; Nano Fe(3)O(4); Saponin; Three-component; copper(II) chloride.

Publication types

Review

MeSH terms

Catalysis
Magnetic Iron Oxide Nanoparticles* / chemistry
Nanocomposites* / chemistry
Naphthols* / chemical synthesis
Saponins* / chemistry
Spectroscopy, Fourier Transform Infrared

Substances

Naphthols
Saponins